B R Green Industries

Clodinafop-Propargyl Technical

Type: Selective Systemic Herbicide

Chemical Category

  • Common Name: Clodinafop-Propargyl
  • Chemical Name (IUPAC): (R)-2-[4-(5-chloro-3-fluoro-2-pyridyloxy)phenoxy]propionic acid, prop-2-ynyl ester
  • Chemical Formula: C₁₇H₁₃ClFNO₄
  • CAS No.: 105512-06-9
  • Chemical Family: Aryloxyphenoxypropionate (FOP) herbicide
  • Type: Post-emergence selective systemic herbicide

 Mode of Action

  • Inhibits the enzyme Acetyl-CoA Carboxylase (ACCase) — essential for lipid synthesis in grasses.
  • This inhibition stops fatty acid biosynthesis, disrupting cell membrane formation in susceptible weeds.
  • Causes growth inhibition, chlorosis, and death of grass weeds while being safe to broadleaf crops (e.g., wheat).
  • Absorbed through leaves, translocated to meristematic regions (growing tips).

Applications

  • Used as a post-emergence herbicide for controlling annual and perennial grass weeds in wheat and other cereal crops.
  • Applied 25–35 days after sowing (DAS), when weeds are in the 2–4 leaf stage.
  • Formulations available: 15% WP, 9% EC, 12% EC, and combination products with Metsulfuron or Fenoxaprop.

Weeds Controlled

  • Clodinafop-Propargyl effectively controls a wide range of grass weeds, including:

Technical Overview

 

  • Physical Form: Crystalline solid or powder
  • Color: White to light brown
  • Purity (Technical): Minimum 95% w/w
  • Solubility: Insoluble in water, soluble in organic solvents (xylene, acetone, toluene)
  • Melting Point: 47–49°C
  • Vapor Pressure: Very low (stable)

Main Uses

 

  • Crop: Wheat (main crop), Barley, Oats (in some regions)
  • Purpose: Control of grassy weeds selectively, ensuring clean crop stands.

 

Storage and Stability

  • Store in cool, dry, well-ventilated area away from sunlight and moisture.
  • Keep in original sealed containers.
  • Avoid storage near food, feed, or strong oxidizing materials.

Stability:

  • Stable for minimum 2 years under normal conditions.
  • Avoid alkaline pH solutions — hydrolysis occurs under high pH (>8).